Facile Reductive Silylation of UO2 2+ to Uranium(IV) Chloride
نویسندگان
چکیده
منابع مشابه
Concerted reductive coupling of an alkyl chloride at Pt(IV).
Oxidation of a doubly cyclometallated platinum(II) complex results in two isomeric platinum(IV) complexes. Whereas the trans isomer is robust, being manipulable in air at room temperature, the cis isomer decomposes at -20 °C and above. Reductive coupling of an alkyl chloride at the cis isomer gives a new species which can be reoxidised. The independence of this coupling on additional halide rul...
متن کاملAcetylene Inhibition of Trichloroethene and Vinyl Chloride Reductive Dechlorination
Kinetic studies reported here have shown that acetylene is a potent reversible inhibitor of reductive dehalogenation of trichloroethene (TCE) and vinyl chloride (VC) by a mixed dehalogenating anaerobic culture. The mixed culture was enriched from a contaminated site in Corvallis, OR, and exhibited methanogenic, acetogenic, and reductive dehalogenation activities. The H2-fed culture transformed ...
متن کاملAcetylene inhibition of trichloroethene and vinyl chloride reductive dechlorination.
Kinetic studies reported here have shown that acetylene is a potent reversible inhibitor of reductive dehalogenation of trichloroethene (TCE) and vinyl chloride (VC) by a mixed dehalogenating anaerobic culture. The mixed culture was enriched from a contaminated site in Corvallis, OR, and exhibited methanogenic, acetogenic, and reductive dehalogenation activities. The H2-fed culture transformed ...
متن کاملPhotoinitiated Oxidative Addition of CF3I to Gold(I) and Facile Aryl-CF3 Reductive Elimination
Herein we report the mechanism of oxidative addition of CF3I to Au(I), and remarkably fast Caryl-CF3 bond reductive elimination from Au(III) cations. CF3I undergoes a fast, formal oxidative addition to R3PAuR' (R = Cy, R' = 3,5-F2-C6H4, 4-F-C6H4, C6H5, 4-Me-C6H4, 4-MeO-C6H4, Me; R = Ph, R' = 4-F-C6H4, 4-Me-C6H4). When R' = aryl, complexes of the type R3PAu(aryl)(CF3)I can be isolated and charac...
متن کاملCRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VIII. CRYSTAL STRUCTURES OF Na3Tl3[(UO2)(MoO4)4], Na13–xTl3+x[(UO2)(MoO4)3]4(H2O)6+x (x = 0.1), Na3Tl5[(UO2)(MoO4)3]2(H2O)3 AND Na2[(UO2)(MoO4)2](H2O)4
Crystals of four sodium uranyl molybdates, Na3Tl3[(UO2)(MoO4)4] (1), Na13–xTl3+x[(UO2)(MoO4)3]4(H2O)6+x (x = 0.1) (2), Na3Tl5[(UO2)(MoO4)3]2(H2O)3 (3) and Na2[(UO2)(MoO4)2](H2O)4 (4), have been synthesized by hydrothermal methods. The structure of each was solved and refined on the basis of F2 for all unique data collected using MoK X-radiation and a CCD-based detector. The structure of 1 [orth...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2016
ISSN: 0044-8249
DOI: 10.1002/ange.201609838